Born-oppenheimer approximation near level crossing

نویسندگان

  • Gordon
  • Avron
چکیده

We consider the Born-Oppenheimer problem near conical intersection in two dimensions. For energies close to the crossing energy we describe the wave function near an isotropic crossing and show that it is related to generalized hypergeometric functions 0F3. This function is to a conical intersection what the Airy function is to a classical turning point. As an application we calculate the anomalous Zeeman shift of vibrational levels near a crossing.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

ar X iv : q ua nt - p h / 99 11 12 1 v 1 3 0 N ov 1 99 9 Born - Oppenheimer Approximation near Level Crossing

We consider the Born-Oppenheimer problem near conical intersection in two dimensions. For energies close to the crossing energy we describe the wave function near an isotropic crossing and show that it is related to generalized hypergeometric functions 0 F 3. This function is to a conical intersection what the Airy function is to a classical turning point. As an application we calculate the ano...

متن کامل

ua nt - p h / 99 11 12 1 v 2 2 7 Fe b 20 00 Born - Oppenheimer Approximation near Level Crossing

We consider the Born-Oppenheimer problem near conical intersection in two dimensions. For energies close to the crossing energy we describe the wave function near an isotropic crossing and show that it is related to generalized hypergeometric functions 0 F 3. This function is to a conical intersection what the Airy function is to a classical turning point. As an application we calculate the ano...

متن کامل

Molecular propagation through crossings and avoided crossings of electron energy levels

The time–dependent Born–Oppenheimer approximation describes the quantum mechanical motion of molecular systems. This approximation fails if a wavepacket propagates through an electron energy level crossing or “avoided crossing.” We discuss the various types of crossings and avoided crossings and describe what happens when molecular systems propagate through them. It is not practical to solve th...

متن کامل

0 Born - Oppenheimer Approximation near Level Crossing

We consider the Born-Oppenheimer problem near conical intersection in two dimensions. For energies close to the crossing energy we describe the wave function near an isotropic crossing and show that it is related to generalized hypergeometric functions 0 F 3. This function is to a conical intersection what the Airy function is to a classical turning point. As an application we calculate the ano...

متن کامل

ua nt - p h / 99 11 12 1 v 4 2 9 M ay 2 00 0 Born - Oppenheimer Approximation near Level Crossing

We consider the Born-Oppenheimer problem near conical intersection in two dimensions. For energies close to the crossing energy we describe the wave function near an isotropic crossing and show that it is related to generalized hypergeometric functions 0 F 3. This function is to a conical intersection what the Airy function is to a classical turning point. As an application we calculate the ano...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 85 1  شماره 

صفحات  -

تاریخ انتشار 2000